?

AP® Chemistry

Free Version

Upgrade subject to access all content

Difficult

Periodicity and Structure

APCHEM-LRK6JZ

Elements in the same group of the periodic table often form compounds with similar formulas but not always with similar properties.

For example, members of the carbon family all form dioxides. $C{ O }_{ 2 }$, $Si{ O }_{ 2 }$, $Sn{ O }_{ 2 }$, and $Pb{ O }_{ 2 }$ are all known to exist, but $C{ O }_{ 2 }$ consists of independent gaseous molecules, while $Si{ O }_{ 2 }$ is a network solid, and $Sn{ O }_{ 2 }$ and $Pb{ O }_{ 2 }$ are ionic solids.

Which of the following would NOT help to explain these observations that the four compounds have different properties?

A

Atomic size (radius) generally increases with increasing atomic number within a group.

B

Carbon and silicon are nonmetals, while tin and lead are metals.

C

All four members of the carbon family have ${ s }^{ 2 }{ p }^{ 2 }$ valence configurations.

D

Only carbon can readily form $\pi$-bonds.